First mononuclear organometallics of MoII and MoIII containing terminal hydroxide ligands. X-Ray structure of [Mo(η5-C5H5)(OH)(PMe3) 3]BF4
Résumé
The new complexes [Mo(η5-C5H5)(OH)(PMe3)2] and [Mo(η5-C5H5 )(OH)(PMe3)3]+ are unique examples of electronically unsaturated organometallics of Mo II and Mo III containing terminal hydroxide ligands; they show no tendency to dimerize with formation of hydroxo-bridges.
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