Cross metathesis of (-)-beta-pinene, (-)-limonene and terpenoids derived from limonene with internal olefins - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Applied Catalysis A : General Année : 2021

Cross metathesis of (-)-beta-pinene, (-)-limonene and terpenoids derived from limonene with internal olefins

Résumé

The straightforward functionalization of sterically demanding alpha,alpha-disubstituted double bonds of beta-pinene, (-)-limonene and (-)-limonene terpenoids has been achieved via cross metathesis with internal olefins. The reactions are catalyzed by second generation ruthenium catalysts in dimethyl carbonate as green solvent or under neat conditions. This transformation provides a clean process for the access to functionalized bulky cyclic terpenes where the terminal double bond generates a trisubstituted olefin.

Domaines

Chimie Catalyse
Fichier principal
Vignette du fichier
Fernandes et al - 2021- Cross metathesis of (-)-β-pinene, (-)-limonene_RevisedApplCatalAGen_Manuscript.pdf (876.2 Ko) Télécharger le fichier
Fernandes_RevisedApplCatalAGen_ SI.pdf (1.64 Mo) Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)

Dates et versions

hal-03331355 , version 1 (15-09-2021)

Identifiants

Citer

Luciana Sarmento Fernandes, Dalmo Mandelli, Wagner A. Carvalho, Elsa Caytan, Cedric Fischmeister, et al.. Cross metathesis of (-)-beta-pinene, (-)-limonene and terpenoids derived from limonene with internal olefins. Applied Catalysis A : General, 2021, 623, pp.118284. ⟨10.1016/j.apcata.2021.118284⟩. ⟨hal-03331355⟩
49 Consultations
48 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More