Chalcogen Bonding in Co-Crystals: Activation through 1,4-Perfluorophenylene vs. 4,4 '-Perfluorobiphenylene Cores - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Molecules Année : 2021

Chalcogen Bonding in Co-Crystals: Activation through 1,4-Perfluorophenylene vs. 4,4 '-Perfluorobiphenylene Cores

Résumé

The ability of alkylseleno/alkyltelluroacetylenes such as bis(selenomethylethynyl)-perfluorobenzene (4F-Se) to act as a ditopic chalcogen bond (ChB) donor in co-crystals with ditopic Lewis bases such as 4,4 '-bipyridine is extended here to the octafluorobiphenylene analog, 4,4 '-bis(selenomethylethynyl)-perfluorobiphenyl (8F-Se), with the more electron-rich 4,4 '-bipyridylethane (bpe), showing in the 1:1 (8F-Se)center dot(bpe) co-crystal a shorter and more linear C-Se center dot center dot center dot N ChB interaction than in (4F-Se)center dot(bpe), with Se center dot center dot center dot N distances down to 2.958(2) angstrom at 150 K, i.e., a reduction ratio of 0.85 vs. the van der Waals contact distance.

Domaines

Chimie
Fichier principal
Vignette du fichier
molecules-26-04050-v2.pdf (1.93 Mo) Télécharger le fichier
Origine : Fichiers éditeurs autorisés sur une archive ouverte

Dates et versions

hal-03330992 , version 1 (01-09-2021)

Licence

Paternité

Identifiants

Citer

Arun Dhaka, Olivier Jeannin, Emmanuel Aubert, Enrique Espinosa, Marc Fourmigue. Chalcogen Bonding in Co-Crystals: Activation through 1,4-Perfluorophenylene vs. 4,4 '-Perfluorobiphenylene Cores. Molecules, 2021, 26 (13), pp.4050. ⟨10.3390/molecules26134050⟩. ⟨hal-03330992⟩
47 Consultations
29 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More