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Article Dans Une Revue Journal of Organic Chemistry Année : 2019

s-Tetrazine Dyes: A Facile Generation of Photoredox Organocatalysts for Routine Oxidations

Résumé

A series of organic dyes derived from s-tetrazine have been synthesized, and their photophysical and electrochemical properties are systematically investigated. Testing these compounds as photoredox catalysts in a model oxidative C-S bond cleavage of thioethers has led us to identify new classes of active s-tetrazines. Moreover, some of them can be formed in situ from commercially available 3,6-dichlorotetrazine, making this photocatalyzed C-S bond functionalization simple and highly practical.
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hal-03328321 , version 1 (29-08-2021)

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Tuan Le, Thibaut Courant, Jérémy Merad, Clémence Allain, Pierre Audebert, et al.. s-Tetrazine Dyes: A Facile Generation of Photoredox Organocatalysts for Routine Oxidations. Journal of Organic Chemistry, 2019, 84 (24), pp.16139-16146. ⟨10.1021/acs.joc.9b02454⟩. ⟨hal-03328321⟩
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