Chiral α-P,N Ligands From a Diastereoselective Ph2PH Addition to (η6-Benzaldimine)tricarbonylchromium Complexes - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue European Journal of Organic Chemistry Année : 1999

Chiral α-P,N Ligands From a Diastereoselective Ph2PH Addition to (η6-Benzaldimine)tricarbonylchromium Complexes

Résumé

Chiral α-aminophosphane (α-P–C–N) ligands have been prepared by reversible addition of Ph2PH to tricarbonylchromium benzaldimine complexes (CO)3Cr[η6-o-C6H4(Y)(CH=NR)] (with Y, R = CH3, CH3 or CH2COOCH3; CH3O, CH3 or p-CH3OC6H4; Cl, C6H5), with complete diastereoselectivity. These complexes are stabilized in solution by electron-withdrawing group(s) on the imine.
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hal-03299507 , version 1 (28-07-2021)

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Jacques Andrieu, Clara Baldoli, Stefano Maiorana, Rinaldo Poli, Philippe Richard. Chiral α-P,N Ligands From a Diastereoselective Ph2PH Addition to (η6-Benzaldimine)tricarbonylchromium Complexes. European Journal of Organic Chemistry, 1999, 1999 (11), pp.3095-3097. ⟨10.1002/(SICI)1099-0690(199911)1999:11<3095::AID-EJOC3095>3.0.CO;2-Q⟩. ⟨hal-03299507⟩
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