<?xml version="1.0" encoding="utf-8"?>
<TEI xmlns="http://www.tei-c.org/ns/1.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:hal="http://hal.archives-ouvertes.fr/" xmlns:gml="http://www.opengis.net/gml/3.3/" xmlns:gmlce="http://www.opengis.net/gml/3.3/ce" version="1.1" xsi:schemaLocation="http://www.tei-c.org/ns/1.0 http://api.archives-ouvertes.fr/documents/aofr-sword.xsd">
  <teiHeader>
    <fileDesc>
      <titleStmt>
        <title>HAL TEI export of hal-03293735</title>
      </titleStmt>
      <publicationStmt>
        <distributor>CCSD</distributor>
        <availability status="restricted">
          <licence target="https://creativecommons.org/publicdomain/zero/1.0/">CC0 1.0 - Universal</licence>
        </availability>
        <date when="2026-04-26T06:59:10+02:00"/>
      </publicationStmt>
      <sourceDesc>
        <p part="N">HAL API Platform</p>
      </sourceDesc>
    </fileDesc>
  </teiHeader>
  <text>
    <body>
      <listBibl>
        <biblFull>
          <titleStmt>
            <title xml:lang="en">Alkaline-earth metal-doped perovskites La0.95A0.05MnO3+δ (A = Ca, Sr): New structural and magnetic features revealed by 57Fe Mössbauer spectroscopy and magnetic measurements</title>
            <author role="aut">
              <persName>
                <forename type="first">Diana</forename>
                <surname>Pchelina</surname>
              </persName>
              <idno type="halauthorid">2254215-0</idno>
              <affiliation ref="#struct-302918"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Vera</forename>
                <surname>Sedykh</surname>
              </persName>
              <idno type="halauthorid">2254216-0</idno>
              <affiliation ref="#struct-302918"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Nataliya</forename>
                <surname>Chistyakova</surname>
              </persName>
              <idno type="halauthorid">2254217-0</idno>
              <affiliation ref="#struct-302918"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Vyacheslav</forename>
                <surname>Rusakov</surname>
              </persName>
              <idno type="halauthorid">2254218-0</idno>
              <affiliation ref="#struct-302918"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Yulia</forename>
                <surname>Alekhina</surname>
              </persName>
              <idno type="halauthorid">2254219-0</idno>
              <affiliation ref="#struct-302918"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Alexey</forename>
                <surname>Tselebrovskiy</surname>
              </persName>
              <idno type="halauthorid">2254220-0</idno>
              <affiliation ref="#struct-302918"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Bernard</forename>
                <surname>Fraisse</surname>
              </persName>
              <email type="md5">bde45029c03e485a8718449bca39d025</email>
              <email type="domain">umontpellier.fr</email>
              <idno type="idhal" notation="string">bfraisse</idno>
              <idno type="idhal" notation="numeric">754665</idno>
              <idno type="halauthorid" notation="string">189274-754665</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-4006-5488</idno>
              <idno type="IDREF">https://www.idref.fr/28431692X</idno>
              <idno type="VIAF">https://viaf.org/viaf/17270866</idno>
              <idno type="ISNI">http://isni.org/isni/0000000006896849</idno>
              <affiliation ref="#struct-1087107"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Lorenzo</forename>
                <surname>Stievano</surname>
              </persName>
              <email type="md5">61af6934feedd6f47958a23db2abff06</email>
              <email type="domain">umontpellier.fr</email>
              <ptr type="url" target="http://www.aime.icgm.fr/"/>
              <idno type="idhal" notation="string">loroik</idno>
              <idno type="idhal" notation="numeric">1526</idno>
              <idno type="halauthorid" notation="string">13996-1526</idno>
              <idno type="RESEARCHERID">http://www.researcherid.com/rid/B-7801-2010</idno>
              <idno type="ORCID">https://orcid.org/0000-0001-8548-0231</idno>
              <idno type="IDREF">https://www.idref.fr/14024462X</idno>
              <idno type="RESEARCHERID">http://www.researcherid.com/rid/http://www.researcherid.com/rid/B-7801-2010</idno>
              <affiliation ref="#struct-1087107"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Moulay Tahar</forename>
                <surname>Sougrati</surname>
              </persName>
              <email type="md5">e86137a6f4519b49aa19b15db9b980db</email>
              <email type="domain">gmail.com</email>
              <idno type="idhal" notation="string">m-sougrati</idno>
              <idno type="idhal" notation="numeric">58</idno>
              <idno type="halauthorid" notation="string">369807-58</idno>
              <idno type="ORCID">https://orcid.org/0000-0003-3740-2807</idno>
              <idno type="IDREF">https://www.idref.fr/13408909X</idno>
              <affiliation ref="#struct-1087107"/>
            </author>
            <editor role="depositor">
              <persName>
                <forename>Lorenzo</forename>
                <surname>Stievano</surname>
              </persName>
              <email type="md5">61af6934feedd6f47958a23db2abff06</email>
              <email type="domain">umontpellier.fr</email>
            </editor>
          </titleStmt>
          <editionStmt>
            <edition n="v1" type="current">
              <date type="whenSubmitted">2021-07-21 11:50:58</date>
              <date type="whenModified">2026-01-09 22:32:05</date>
              <date type="whenReleased">2021-07-21 13:11:07</date>
              <date type="whenProduced">2021</date>
              <date type="whenEndEmbargoed">2021-12-08</date>
              <ref type="file" target="https://hal.science/hal-03293735v1/document">
                <date notBefore="2021-12-08"/>
              </ref>
              <ref type="file" subtype="author" n="1" target="https://hal.science/hal-03293735v1/file/JPCS_paper_Pchelina-final.pdf" id="file-3293739-2893874">
                <date notBefore="2021-12-08"/>
              </ref>
            </edition>
            <respStmt>
              <resp>contributor</resp>
              <name key="110342">
                <persName>
                  <forename>Lorenzo</forename>
                  <surname>Stievano</surname>
                </persName>
                <email type="md5">61af6934feedd6f47958a23db2abff06</email>
                <email type="domain">umontpellier.fr</email>
              </name>
            </respStmt>
          </editionStmt>
          <publicationStmt>
            <distributor>CCSD</distributor>
            <idno type="halId">hal-03293735</idno>
            <idno type="halUri">https://hal.science/hal-03293735</idno>
            <idno type="halBibtex">pchelina:hal-03293735</idno>
            <idno type="halRefHtml">&lt;i&gt;Journal of Physics and Chemistry of Solids&lt;/i&gt;, 2021, 159, pp.110268. &lt;a target="_blank" href="https://dx.doi.org/10.1016/j.jpcs.2021.110268"&gt;&amp;#x27E8;10.1016/j.jpcs.2021.110268&amp;#x27E9;&lt;/a&gt;</idno>
            <idno type="halRef">Journal of Physics and Chemistry of Solids, 2021, 159, pp.110268. &amp;#x27E8;10.1016/j.jpcs.2021.110268&amp;#x27E9;</idno>
            <availability status="restricted">
              <licence target="https://about.hal.science/hal-authorisation-v1/">HAL Authorization<ref corresp="#file-3293739-2893874"/></licence>
            </availability>
          </publicationStmt>
          <seriesStmt>
            <idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno>
            <idno type="stamp" n="ENSC-MONTPELLIER">Ecole Nationale Supérieure de Chimie de Montpellier</idno>
            <idno type="stamp" n="ICG">Institut Charles Gerhardt - Institut de Chimie Moléculaire et des Matériaux de Montpellier</idno>
            <idno type="stamp" n="INC-CNRS">Institut de Chimie du CNRS</idno>
            <idno type="stamp" n="CHIMIE">Chimie</idno>
            <idno type="stamp" n="UNIV-MONTPELLIER">Université de Montpellier</idno>
            <idno type="stamp" n="TEST-HALCNRS">Collection test HAL CNRS</idno>
            <idno type="stamp" n="UM-2015-2021" corresp="UNIV-MONTPELLIER">Université de Montpellier (2015-2021)</idno>
            <idno type="stamp" n="TEST2-HALCNRS">TEST2-HALCNRS</idno>
          </seriesStmt>
          <notesStmt>
            <note type="audience" n="2">International</note>
            <note type="popular" n="0">No</note>
            <note type="peer" n="1">Yes</note>
          </notesStmt>
          <sourceDesc>
            <biblStruct>
              <analytic>
                <title xml:lang="en">Alkaline-earth metal-doped perovskites La0.95A0.05MnO3+δ (A = Ca, Sr): New structural and magnetic features revealed by 57Fe Mössbauer spectroscopy and magnetic measurements</title>
                <author role="aut">
                  <persName>
                    <forename type="first">Diana</forename>
                    <surname>Pchelina</surname>
                  </persName>
                  <idno type="halauthorid">2254215-0</idno>
                  <affiliation ref="#struct-302918"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Vera</forename>
                    <surname>Sedykh</surname>
                  </persName>
                  <idno type="halauthorid">2254216-0</idno>
                  <affiliation ref="#struct-302918"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Nataliya</forename>
                    <surname>Chistyakova</surname>
                  </persName>
                  <idno type="halauthorid">2254217-0</idno>
                  <affiliation ref="#struct-302918"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Vyacheslav</forename>
                    <surname>Rusakov</surname>
                  </persName>
                  <idno type="halauthorid">2254218-0</idno>
                  <affiliation ref="#struct-302918"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Yulia</forename>
                    <surname>Alekhina</surname>
                  </persName>
                  <idno type="halauthorid">2254219-0</idno>
                  <affiliation ref="#struct-302918"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Alexey</forename>
                    <surname>Tselebrovskiy</surname>
                  </persName>
                  <idno type="halauthorid">2254220-0</idno>
                  <affiliation ref="#struct-302918"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Bernard</forename>
                    <surname>Fraisse</surname>
                  </persName>
                  <email type="md5">bde45029c03e485a8718449bca39d025</email>
                  <email type="domain">umontpellier.fr</email>
                  <idno type="idhal" notation="string">bfraisse</idno>
                  <idno type="idhal" notation="numeric">754665</idno>
                  <idno type="halauthorid" notation="string">189274-754665</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-4006-5488</idno>
                  <idno type="IDREF">https://www.idref.fr/28431692X</idno>
                  <idno type="VIAF">https://viaf.org/viaf/17270866</idno>
                  <idno type="ISNI">http://isni.org/isni/0000000006896849</idno>
                  <affiliation ref="#struct-1087107"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Lorenzo</forename>
                    <surname>Stievano</surname>
                  </persName>
                  <email type="md5">61af6934feedd6f47958a23db2abff06</email>
                  <email type="domain">umontpellier.fr</email>
                  <ptr type="url" target="http://www.aime.icgm.fr/"/>
                  <idno type="idhal" notation="string">loroik</idno>
                  <idno type="idhal" notation="numeric">1526</idno>
                  <idno type="halauthorid" notation="string">13996-1526</idno>
                  <idno type="RESEARCHERID">http://www.researcherid.com/rid/B-7801-2010</idno>
                  <idno type="ORCID">https://orcid.org/0000-0001-8548-0231</idno>
                  <idno type="IDREF">https://www.idref.fr/14024462X</idno>
                  <idno type="RESEARCHERID">http://www.researcherid.com/rid/http://www.researcherid.com/rid/B-7801-2010</idno>
                  <affiliation ref="#struct-1087107"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Moulay Tahar</forename>
                    <surname>Sougrati</surname>
                  </persName>
                  <email type="md5">e86137a6f4519b49aa19b15db9b980db</email>
                  <email type="domain">gmail.com</email>
                  <idno type="idhal" notation="string">m-sougrati</idno>
                  <idno type="idhal" notation="numeric">58</idno>
                  <idno type="halauthorid" notation="string">369807-58</idno>
                  <idno type="ORCID">https://orcid.org/0000-0003-3740-2807</idno>
                  <idno type="IDREF">https://www.idref.fr/13408909X</idno>
                  <affiliation ref="#struct-1087107"/>
                </author>
              </analytic>
              <monogr>
                <idno type="halJournalId" status="VALID">16019</idno>
                <idno type="issn">0022-3697</idno>
                <title level="j">Journal of Physics and Chemistry of Solids</title>
                <imprint>
                  <publisher>Elsevier</publisher>
                  <biblScope unit="volume">159</biblScope>
                  <biblScope unit="pp">110268</biblScope>
                  <date type="datePub">2021</date>
                  <date type="dateEpub">2021-06-08</date>
                </imprint>
              </monogr>
              <idno type="doi">10.1016/j.jpcs.2021.110268</idno>
            </biblStruct>
          </sourceDesc>
          <profileDesc>
            <langUsage>
              <language ident="en">English</language>
            </langUsage>
            <textClass>
              <keywords scheme="author">
                <term xml:lang="en">perovskites</term>
                <term xml:lang="en">doped lanthanum manganites</term>
                <term xml:lang="en">Mössbauer spectroscopy</term>
                <term xml:lang="en">phase separation</term>
                <term xml:lang="en">magnetic properties</term>
                <term xml:lang="en">superparamagnetism.</term>
              </keywords>
              <classCode scheme="halDomain" n="chim.mate">Chemical Sciences/Material chemistry</classCode>
              <classCode scheme="halTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halOldTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halTreeTypology" n="ART">Journal articles</classCode>
            </textClass>
            <abstract xml:lang="en">
              <p>Ca- and Sr-doped lanthanum manganese perovskites La0.95A0.05Mn0.98Fe0.02O3+δ (A = Ca, Sr) (LCM and LSM) of non-stoichiometric (NS) and stoichiometric (S) compositions were prepared by sol-gel method and investigated by 57Fe Mössbauer spectroscopy and magnetic measurements. In contrast to non-stoichiometric samples, which contain pure singles phases, a mixture of orthorhombic phases O (PnmaI), O′ (PnmaII)and O′′ (PnmaII*)are detected in samples of stoichiometric compositions. The magnetic data, supported by Mössbauer measurements, show the spontaneous formation of magnetically ordered clusters with sizes in the range 2.5–4.6 nm in all samples. The main differences between the investigated LCM and LSM systems, and in particular the less extended phase separation in LSM-S than in LCM-S is connected to the difference in ionic radii on the doping ions, the influence of the Jahn-Teller effect at the Mn+3 centres and the size distributions of the ferromagnetic clusters. Our results show, for the first time, that the O′′ (PnmaII*) phase is characterized by antiferromagnetic ordering.</p>
            </abstract>
          </profileDesc>
        </biblFull>
      </listBibl>
    </body>
    <back>
      <listOrg type="structures">
        <org type="institution" xml:id="struct-302918" status="VALID">
          <idno type="ISNI">0000 0001 1847 9169</idno>
          <idno type="ROR">https://ror.org/010pmpe69</idno>
          <orgName>Lomonosov Moscow State University = Université d'État Lomonossov de Moscou</orgName>
          <orgName type="acronym">MSU</orgName>
          <date type="start">1755-01-01</date>
          <desc>
            <address>
              <addrLine>GSP-1, Leninskie Gory, Moscow, 119991, Russian Federation</addrLine>
              <country key="RU"/>
            </address>
            <ref type="url">http://www.msu.ru/en/</ref>
          </desc>
        </org>
        <org type="laboratory" xml:id="struct-1087107" status="OLD">
          <idno type="ISNI">0000000123688723</idno>
          <idno type="RNSR">200711918D</idno>
          <idno type="ROR">https://ror.org/028wq3277</idno>
          <orgName>Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier</orgName>
          <orgName type="acronym">ICGM</orgName>
          <date type="start">2015-01-01</date>
          <date type="end">2021-12-31</date>
          <desc>
            <address>
              <addrLine>Place Eugène Bataillon - Bâtiment 17 - CC1700- 34095 Montpellier cedex 5</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.icgm.fr/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-300370" type="direct"/>
            <relation active="#struct-341038" type="direct"/>
            <relation active="#struct-410122" type="direct"/>
            <relation name="UMR5253" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-300370" status="OLD">
          <idno type="ROR">https://ror.org/03sgyqj04</idno>
          <orgName>Ecole Nationale Supérieure de Chimie de Montpellier</orgName>
          <orgName type="acronym">ENSCM</orgName>
          <date type="end">2021-12-31</date>
          <desc>
            <address>
              <addrLine>8 Rue de l'Ecole Normale 34296 Montpellier Cedex 5</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.enscm.fr</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-341038" status="VALID">
          <idno type="IdRef">232435103</idno>
          <idno type="ISNI">000000010626358X</idno>
          <idno type="ROR">https://ror.org/02cte4b68</idno>
          <orgName>Institut de Chimie - CNRS Chimie</orgName>
          <orgName type="acronym">INC-CNRS</orgName>
          <date type="start">2009-10-01</date>
          <desc>
            <address>
              <addrLine>CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE3 rue Michel-Ange75794 PARIS CEDEX 16 - France</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.cnrs.fr/inc</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-410122" status="OLD">
          <idno type="ISNI">0000000120970141</idno>
          <idno type="ROR">https://ror.org/051escj72</idno>
          <orgName>Université de Montpellier</orgName>
          <orgName type="acronym">UM</orgName>
          <date type="end">2021-12-31</date>
          <desc>
            <address>
              <addrLine>163 rue Auguste Broussonnet - 34090 Montpellier</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.umontpellier.fr/</ref>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-441569" status="VALID">
          <idno type="IdRef">02636817X</idno>
          <idno type="ISNI">0000000122597504</idno>
          <idno type="ROR">https://ror.org/02feahw73</idno>
          <orgName>Centre National de la Recherche Scientifique</orgName>
          <orgName type="acronym">CNRS</orgName>
          <date type="start">1939-10-19</date>
          <desc>
            <address>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.cnrs.fr/</ref>
          </desc>
        </org>
      </listOrg>
    </back>
  </text>
</TEI>