Cyclopentadienylmolybdenum(VI) and Molybdenum(V) Oxo Chemistry: New Synthetic and Structural Features - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue European Journal of Inorganic Chemistry Année : 2002

Cyclopentadienylmolybdenum(VI) and Molybdenum(V) Oxo Chemistry: New Synthetic and Structural Features

Résumé

Convenient syntheses for Cp, Cp*, and related cyclopentadienyl derivatives (4Cp = C5HiPr4; Cp′′′ = C5H2tBu3-1,2,4) of formula [(Ring)2Mo2O5] are described. Compound [Cp2Mo2O5] was produced in good yields by the rapid oxidation of red [CpMoO2]4 with PhIO in CH2Cl2. [Cp*2Mo2O5] was obtained by CH3COOH acidification of aqueous solutions of [Cp*MoO3]−Na+, the latter being generated in a single step from [Cp*MoCl4] and more than 5 equiv. of aqueous NaOH in air. Minor quantities of [Cp*MoO2]2 were also isolated from this reaction, although the formation of this by-product may be reduced by using a two-step basic hydrolysis procedure. Extension of the latter strategy also allowed the preparation of [4Cp2Mo2O5], [Cp′′′2Mo2O5], and [4CpMoO2Cl] in good yields, in addition to the by-product [Cp′′′MoO2]2. X-ray structures are reported for compounds [4Cp2Mo2O5], [Cp′′′2Mo2O5], [Cp*MoO2]2, [Cp′′′MoO2]2, and [4CpMoO2Cl]
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Dates et versions

hal-03284357 , version 1 (20-07-2021)

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Dirk Saurenz, Funda Demirhan, Philippe Richard, Rinaldo Poli, Helmut Sitzmann. Cyclopentadienylmolybdenum(VI) and Molybdenum(V) Oxo Chemistry: New Synthetic and Structural Features. European Journal of Inorganic Chemistry, 2002, 2002 (6), pp.1415-1424. ⟨10.1002/1099-0682(200206)2002:6<1415::AID-EJIC1415>3.0.CO;2-V⟩. ⟨hal-03284357⟩
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