Ten years of L-band radiometric measurements have proven the capability of satellite sea surface salinity (SSS) to resolve large-scale-to-mesoscale SSS features in tropical to subtropical ocean. In mid-to-high latitudes, L-band measurements still suffer from large-scale and time-varying errors. Here, a simple method is proposed to mitigate the large-scale and time-varying errors. First, an optimal interpolation using a large correlation scale (~500 km) is used to map independently Soil Moisture Ocean Salinity (SMOS) and Soil Moisture Active Passive (SMAP) level-3 (L3) data. The mapping is compared with the equivalent mapping of in situ observations to estimate the large-scale and seasonal biases. A second mapping is performed on adjusted SSS at the scale of SMOS/SMAP spatial resolution (~45 km). This procedure merges both products and increases the signal-to-noise ratio of the absolute SSS estimates, reducing the root-mean-square difference of in situ satellite products by about 26%–32% from mid- to high latitudes, respectively, in comparison with the existing SMOS and SMAP L3 products. However, in the Arctic Ocean, some issues on satellite retrieved SSS related to, for example, radio frequency interferences, land–sea contamination, and ice–sea contamination remain challenging to reduce given the low sensitivity of L-band radiometric measurements to SSS in cold water. Using the International Thermodynamic Equation Of Seawater—2010 (TEOS-10), the resulting level-4 SSS satellite product is combined with satellite-microwave SST products to estimate sea surface density, spiciness, and haline contraction and thermal expansion coefficients. For the first time, we illustrate how useful these satellite-derived parameters are to fully characterize the surface ocean water masses at large mesoscale.