A decatungstate-based Ionic liquid exhibiting very low dielectric constant suitable for acting as solvent and catalyst for oxidation of organic substrates - Archive ouverte HAL
Article Dans Une Revue New Journal of Chemistry Année : 2021

A decatungstate-based Ionic liquid exhibiting very low dielectric constant suitable for acting as solvent and catalyst for oxidation of organic substrates

Résumé

In this contribution, a new POM-based ionic liquid, namely (P6,6,6,14)4[W10O32], was fully characterized. Its viscosity and its very low dielectric constant make this hybrid ionic liquid suitable to be used as solvent for organic transformations. As proof of concept, this unique ionic liquid combining solvant and catalyst properties was tested for catalytic oxidation of various alcohols and alkenes in presence of H2O2
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Dates et versions

hal-03231821 , version 1 (21-05-2021)

Identifiants

Citer

Yohan Martinetto, Bruce Pégot, Catherine Roch, Mohamed Haouas, Betty Cottyn Boitte, et al.. A decatungstate-based Ionic liquid exhibiting very low dielectric constant suitable for acting as solvent and catalyst for oxidation of organic substrates. New Journal of Chemistry, 2021, 45 (22), pp.9751-9755. ⟨10.1039/D1NJ01214B⟩. ⟨hal-03231821⟩
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