Manganese – new prominent actor in transfer hydrogenation catalysis - Archive ouverte HAL
Journal Articles Current opinion in green and sustainable chemistry Year : 2021

Manganese – new prominent actor in transfer hydrogenation catalysis

Abstract

Transfer hydrogenation processes catalyzed by manganese organometallic complexes are comprehensively reviewed. The reaction scope includes the reduction of aldehydes, ketones, imines, polyaromatic nitrogen heterocycles, esters, nitriles and semi-hydrogenation of internal alkynes. Special attention is devoted to ligand design for Mn-catalyzed asymmetric transfer hydrogenation of prochiral ketones leading to enantiomerically-enriched alcohols.
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hal-03230650 , version 1 (04-06-2021)

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Karim Azouzi, Dmitry A. Valyaev, Stéphanie Bastin, Jean-Baptiste Sortais. Manganese – new prominent actor in transfer hydrogenation catalysis. Current opinion in green and sustainable chemistry, 2021, 31, pp.100511. ⟨10.1016/j.cogsc.2021.100511⟩. ⟨hal-03230650⟩
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