Hybrids of cationic [4]helicene and N-heterocyclic carbene as ligands for complexes exhibiting (chir)optical properties in the far red spectral window - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Chemical Communications Année : 2021

Hybrids of cationic [4]helicene and N-heterocyclic carbene as ligands for complexes exhibiting (chir)optical properties in the far red spectral window

Résumé

Synthesis, electronic and structural properties of a chiral NHC bearing a N-bonded cationic [4]helicene moiety are reported. This ligand is used to construct Au, Au and Rh complexes exhibiting far-red (chir)optical properties regardless of the metal.

Domaines

Chimie
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Origine : Publication financée par une institution

Dates et versions

hal-03223791 , version 1 (26-05-2021)

Identifiants

Citer

Robert Tarrieu, Irene Hernandez Delgado, Francesco Zinna, Vincent Dorcet, Sophie Colombel-Rouen, et al.. Hybrids of cationic [4]helicene and N-heterocyclic carbene as ligands for complexes exhibiting (chir)optical properties in the far red spectral window. Chemical Communications, 2021, 57 (31), pp.3793-3796. ⟨10.1039/d1cc00898f⟩. ⟨hal-03223791⟩
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