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Article Dans Une Revue Coordination Chemistry Reviews Année : 2008

High oxidation state organomolybdenum and organotungsten chemistry in protic environments

Rinaldo Poli

Résumé

The chemistry of organomolybdenum and -tungsten compounds in high oxidation states (mostly V and VI) is reviewed, with special attention on the behaviour in protic media and with respect to protic reagents. The high metal–carbon bond covalency imparts a great degree of inertness to these bonds relative to protonolysis. Hence, extensive chemistry in a wide variety of media and with protic reagents is possible without affecting the metal–(hydrocarbyl ligand) interactions. This article does not cover metallocene [i.e. bis(cyclopentadienyl)], alkylidene and alkylidyne derivatives, that have been extensively covered in other recent reviews.
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hal-03192719 , version 1 (08-04-2021)

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Rinaldo Poli. High oxidation state organomolybdenum and organotungsten chemistry in protic environments. Coordination Chemistry Reviews, 2008, 252 (15-17), pp.1592-1612. ⟨10.1016/j.ccr.2007.11.029⟩. ⟨hal-03192719⟩
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