Palladium and platinum complexes with planar chiral 1,2-disubstituted ferrocenes containing phosphine and thioether donor groups
Résumé
Three palladium(II) complexes and four platinum(II) complexes having general formula CpFe{1,2-C5H3(PPh2)(CH2SR)}MCl2 (M = Pd, R = Ph, Et and tBu; M = Pt, R = Ph, Et, tBu and Cy) have been synthesized by reaction of the corresponding CpFe{1,2-C5H3(PPh2)(CH2SR)} ligands with PdCl2(CH3CN)2 or PtCl2(CH3CN)2. These complexes have been fully characterized in solution and in solid state. In all cases, monomeric square planar complexes were obtained as pure diastereoisomers.
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245-10.1016-j.jorganchem.2007.08.021-Accepted.pdf (946.62 Ko)
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