Interactions between Halothiobacillus neapolitanus and mortars: Comparison of the biodeterioration between Portland cement and calcium aluminate cement - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue International Biodeterioration and Biodegradation Année : 2017

Interactions between Halothiobacillus neapolitanus and mortars: Comparison of the biodeterioration between Portland cement and calcium aluminate cement

Résumé

Biodeterioration of mortars made either with ordinary Portland cement or calcium aluminate cement by Halothiobacillus neapolitanus was investigated by bioleaching experiments. Mortar deterioration, determined by a leaching coefficient calculated with the amounts of chemical elements leached from the mortar to the bacterial suspension, was greater for ordinary Portland cement. The amount of biogenerated sulfuric acid, estimated by the consumption of sulfur-containing components, varied markedly due to the interactions between H. neapolitanus and the mortar that depended on two main mechanisms. First, the different mineralogy of both cement pastes led to a weaker acid-neutralizing capacity of calcium aluminate cement in the pH range 6.5 to 3. Second, a restricted oxidation of tetrathionate by H. neapolitanus, that limited the biogeneration of sulfuric acid, was observed when pH approached 3 more rapidly. Consequently, the weaker acid-neutralizing capacity of calcium aluminate cement induced a quicker drop of the pH of the bacterial suspension from 6.5 to 3, leading to a decrease of the amount of biogenerated sulfuric acid. Thus, calcium aluminate cement mortar in the presence of H. neapolitanus bacterial suspension was less deteriorated than ordinary Portland cement mortar in the pH range considered.

Domaines

Génie civil
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Dates et versions

hal-03185569 , version 1 (30-03-2021)

Identifiants

Citer

Christine Lors, Eminence Dorelle Hondjuila Miokono, Denis Damidot. Interactions between Halothiobacillus neapolitanus and mortars: Comparison of the biodeterioration between Portland cement and calcium aluminate cement. International Biodeterioration and Biodegradation, 2017, 121, pp.19-25. ⟨10.1016/j.ibiod.2017.03.010⟩. ⟨hal-03185569⟩
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