A Photochemical Strategy for Carbon Isotope Exchange with CO 2
Résumé
A photocatalytic approach for carbon isotope exchange is reported. Utilizing [ 13 C]CO2 and [ 14 C]CO2 as primary C1 sources, this protocol allows the insertion of the desired carbon isotope into phenyl acetic acids without the need of structural modifications or prefunctionalization, in one single step. The exceptionally mild conditions required for this traceless transformation are in stark contrast with previous methods requiring the use of harsh thermal conditions.
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