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Article Dans Une Revue Inorganica Chimica Acta Année : 2021

Synthesis, structure and magnetic properties of an oxamate-based 1D coordination polymer built on pentametallic links

Résumé

The solvothermal reaction of the hexadentate 2-(oxamato)benzoic acid ligand (oaba) with copper(II) and cobalt(II) ions has yielded the [Cu4Co3(oaba)4(OH)2(DMF)6]•2(DMF)•1H2O (1) 1D coordination polymer. The single-crystal X-ray diffraction study reveals the formation of a neutral chain built from pentametallic complexes where each multi-polydentate ligand bridges four metal centres. The atypical morphology observed here for an oxamate-based 1D polymer arises from the use of a ligand bearing extra coordination sites. Magnetometry indicates strong dominating antiferromagnetic interactions within the polymer resulting in a non-zero ferrimagnetic state at low temperature.
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hal-03159605 , version 1 (04-03-2021)

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Ang Li, Jérémy Forté, Yanling Li, Yves Journaux, Laurent Lisnard. Synthesis, structure and magnetic properties of an oxamate-based 1D coordination polymer built on pentametallic links. Inorganica Chimica Acta, 2021, ⟨10.1016/j.ica.2021.120320⟩. ⟨hal-03159605⟩
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