Access to functionalized luminescent Pt(ii) complexes by photoredox-catalyzed Minisci alkylation of 6-aryl-2,2′-bipyridines
Résumé
Photoredox-mediated C-H bond alkylation of 6-aryl-2,2′-bipyridines withN-(acyloxy)phthalimides is reported. The reaction exhibits excellent functional group tolerance, including chiral aliphatic groups. The influence of the incorporatedC6′-alkyl group on the photophysical properties of the corresponding (N^N^C) cyclometalated Pt(ii) complexes is described, including chiroptical properties.
Domaines
Chimie de coordination
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Hagui-2021-Access to functionalized luminescent Pt(II) complexes by.pdf (2.23 Mo)
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