Access to functionalized luminescent Pt(ii) complexes by photoredox-catalyzed Minisci alkylation of 6-aryl-2,2′-bipyridines - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Chemical Communications Année : 2021

Access to functionalized luminescent Pt(ii) complexes by photoredox-catalyzed Minisci alkylation of 6-aryl-2,2′-bipyridines

Résumé

Photoredox-mediated C-H bond alkylation of 6-aryl-2,2′-bipyridines withN-(acyloxy)phthalimides is reported. The reaction exhibits excellent functional group tolerance, including chiral aliphatic groups. The influence of the incorporatedC6′-alkyl group on the photophysical properties of the corresponding (N^N^C) cyclometalated Pt(ii) complexes is described, including chiroptical properties.
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Dates et versions

hal-03157991 , version 1 (07-04-2021)

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W. Hagui, Marie Cordier, J. Boixel, Jean-François Soulé. Access to functionalized luminescent Pt(ii) complexes by photoredox-catalyzed Minisci alkylation of 6-aryl-2,2′-bipyridines. Chemical Communications, 2021, 57 (8), pp.1038-1041. ⟨10.1039/d0cc07307e⟩. ⟨hal-03157991⟩
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