Synthesis and reactivity of phosphine borohydride compounds - Archive ouverte HAL
Journal Articles Chemical Communications Year : 2021

Synthesis and reactivity of phosphine borohydride compounds

Abstract

Four lithium phosphine borohydride compounds featuring phenyl and naphthyl linkers have been synthesized. In-depth NMR analysis affords evidence for non-bonded through space P–B coupling. Reactivity towards CO2 leads to LiH transfer and to the quantitative formation of the corresponding ambiphilic phosphine–borane products.
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hal-03149993 , version 1 (23-02-2021)

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Ramaraj Ayyappan, Yannick Coppel, Laure Vendier, Sundargopal Ghosh, Sylviane Sabo-Etienne, et al.. Synthesis and reactivity of phosphine borohydride compounds. Chemical Communications, 2021, 57 (3), pp.375-378. ⟨10.1039/D0CC07072F⟩. ⟨hal-03149993⟩
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