Physical properties of electrodeposited CIGS films on crystalline silicon: Application for photovoltaic hetero-junction - Archive ouverte HAL
Article Dans Une Revue Current Applied Physics Année : 2019

Physical properties of electrodeposited CIGS films on crystalline silicon: Application for photovoltaic hetero-junction

Résumé

P-type CIGS (CuIn 1-x Ga x Se 2) thin films are electro-deposited on a p-type c-Si substrate with a galvanostatic mode to form CIGS(p)/c-Si(p) hetero-junction. The Ga content is varied up to x = 30%. The physical properties of formed CIGS films are characterized by XRD, SEM, EDS and UV-Visible spectroscopy. With x = 30%, we obtain a single chalcopyrite phase of CIGS with a tetragonal crystal structure, a high crystallinity, an orientation toward the (112) direction and a band gap energy of 1.40 eV. AM1.5 J-V performed on the CuI 0.7 G 0.3 Se 2 /c-Si hetero-junction reveals interesting photovoltaic parameters with an efficiency of 3.75%. In addition, using the energy diagram of the hetero-junction calculated with the Anderson model, we show that it could play a dual role when combined to a c-Si cell in a Ag-Al/c-Si(n +)/c-Si (p)/CIGS(p)/Al new architecture. Therefore, in addition to its interesting photovoltaic parameters, this heterojunction can substitute the BSF.

Domaines

Matériaux
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Dates et versions

hal-03141578 , version 1 (15-02-2021)

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H. Saïdi, C. Ben Alaya, M. F. Boujmil, B. Durand, J.-L. Lazzari, et al.. Physical properties of electrodeposited CIGS films on crystalline silicon: Application for photovoltaic hetero-junction. Current Applied Physics, 2019, 20 (1), pp.29 - 36. ⟨10.1016/j.cap.2019.09.015⟩. ⟨hal-03141578⟩
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