Effect of chromium substitution on structural, magnetic and magnetocaloric properties of GdFe12−Cr intermetallic compounds, Mössbauer spectrometry and ab initio calculations - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Journal of Solid State Chemistry Année : 2021

Effect of chromium substitution on structural, magnetic and magnetocaloric properties of GdFe12−Cr intermetallic compounds, Mössbauer spectrometry and ab initio calculations

Résumé

The single-phase intermetallic compounds GdFe12−xCrx (x ​= ​2, 2.5 and 3), elaborated by arc-melting method and annealed at 1073 ​K, crystallize in the ThMn12-type structure with the space group. The structural, magnetic and magnetocaloric properties of these intermetallic compounds were studied extensively by means of X-ray powder diffraction (XRD), Mössbauer spectrometry and magnetic measurements. The Rietveld analysis of X-ray diffraction patterns reveals that the lattice parameters of GdFe12−xCrx (x ​= ​2, 2.5 and 3) compounds increase linearly with increasing Cr content up to x ​= ​3, and proves that Cr atom prefers sites in the ThMn12 structure and that Fe occupies , and . The Mössbauer spectra study based on the Wigner-Seitz cell volumes correlation with the isomer shift parameter of each specific site , and , confirms the preferred inequivalent crystallographic site of Cr atoms. Ab initio calculations of GdFe12−xCrx were performed using the density functional theory (DFT) based on the full potential linearized augmented plane wave (FLAPW). The calculated data are in good agreement with the results of the magnetic measurements as well as with the Mössbauer spectrometry. The variation of magnetization (M) vs. temperature (T) reveals that all compounds exhibit a second-order ferromagnetic to paramagnetic phase transition in the vicinity of the Curie temperature (). The substitution of Fe by Cr yields enhancement of the magnetic ordering transition temperature. The maximum magnetic entropy change () was estimated from isothermal magnetization curves and it increases from 1.82 ​J/kg.K for x ​= ​2, to 2.95 ​J/kg.K for x ​= ​3, under a field change of 1.5 ​T. The relative cooling power (RCP) is in the range of 12.5 ​J/kg for x ​= ​2 and 30.4 ​J/kg for x ​= ​3. Our results suggest that such substituted compounds could be considered as a potential candidate for magnetic refrigeration technology.
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hal-03984347 , version 1 (09-03-2023)

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Paternité - Pas d'utilisation commerciale

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M. Saidi, S. Walha, E.K. Hlil, Lotfi Bessais, M. Jemmali. Effect of chromium substitution on structural, magnetic and magnetocaloric properties of GdFe12−Cr intermetallic compounds, Mössbauer spectrometry and ab initio calculations. Journal of Solid State Chemistry, 2021, 297, pp.122019. ⟨10.1016/j.jssc.2021.122019⟩. ⟨hal-03984347⟩
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