A Journey in Lanthanide Coordination Chemistry: From Evaporable Dimers to Magnetic Materials and Luminescent Devices - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Accounts of Chemical Research Année : 2021

A Journey in Lanthanide Coordination Chemistry: From Evaporable Dimers to Magnetic Materials and Luminescent Devices

Résumé

Conspectus. Lanthanide ions are prime ingredients for the design of compounds, materials, and devices with unique magnetic and optical properties. Accordingly, coordination chemistry is one of the best tools for building molecular edifices from these ions because it allows careful control of the ions’ environment and of the dimensionality of the final compound.In this Account, we review our results on lanthanide-based dimers. We show how a pure fundamental study on lanthanide coordination chemistry allows the investigation of a full continuum of results from the compound to materials and then to devices. The conversion of molecules into materials is a tricky task because it requires strong molecular robustness toward the surface deposition processes as well as the preservation and detectability of the molecular properties in the material. Additionally, the passage of a material toward a device implies a material with a given function, for example, a tailored response to an external stimulus.To do so, we targeted neutral and isolated molecules whose transfer on surfaces by chemi- or physisorption is much easier than that of charged molecules or extended coordination networks. Then, we focused on molecules with very strong evaporability to avoid wet chemistry deposition processes that are more likely to damage the molecules and/or distort their geometries.We thus designed lanthanide dimers based on fluorinated β-diketonates and pyridine-N-oxide ligands. As expected, they show remarkable evaporability but also strong luminescence and interesting magnetic behavior because they behave as single-molecule magnets (SMMs). Ligand substitutions and stoichiometric modifications allow the optimization of the geometric organization of the dimers in the crystal packing as well as their evaporability, SMM behavior, luminescent properties, or their ability to be anchored on surfaces. Most of all, this family of molecules shows a strong ability to form thick films on various substrates. This allows converting these molecules to magnetic materials and luminescent devices.Magnetic materials can be designed by creating thick films of the dimers deposited on gold. These films have been designed and investigated with the most advanced techniques of on-surface imaging (atomic force microscopy, AFM), on-surface physicochemical characterization (X-ray photoelectron spectroscopy (XPS), time of flight-secondary ion mass spectroscopy (Tof-SIMS)), and on-surface magnetic investigation (low-energy muon spin relaxation (LE-μSR)). Contrary to what was previously observed on other SMM films, no depth dependence of the SMM behavior was observed. This means that the dimers do not suffer from the vacuum or substrate interface and behave similarly, whatever their localization. This exceptional magnetic robustness is a key ingredient in the creation of materials for molecular magnetic data storage.Luminescent devices can be obtained by layering molecular films of the dimers with a copper-rich solid-state electrolyte between ITO/Pt electrodes. The electromigration of Cu(2+) ions into films of Eu(3+), Tb(3+), and Dy(3+) dimers quenches their luminescence. This luminescence tuning by electromigration is reversible, and this setup can be considered to be a proof of concept of full solid-state luminescent device where reversible coding can be tailored by an electric field. It is envisioned for optical data storage purposes. In the future, it could also benefit from the SMM properties of the molecules to pave the way toward multifunctional molecular data storage devices.

Domaines

Chimie
Fichier principal
Vignette du fichier
Bernot et al - 2021 - A Journey in Lanthanide Coordination Chemistry.pdf (3.21 Mo) Télécharger le fichier
Bernot SI.pdf (591.3 Ko) Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)

Dates et versions

hal-03128529 , version 1 (22-02-2021)

Identifiants

Citer

Kevin Bernot, Carole Daiguebonne, Guillaume Calvez, Yan Suffren, Olivier Guillou. A Journey in Lanthanide Coordination Chemistry: From Evaporable Dimers to Magnetic Materials and Luminescent Devices. Accounts of Chemical Research, 2021, 54 (2), pp.427-440. ⟨10.1021/acs.accounts.0c00684⟩. ⟨hal-03128529⟩
118 Consultations
323 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More