Made-to-order porous electrodes for supercapacitors: MOFs embedded with redox-active centers as a case study - Archive ouverte HAL
Article Dans Une Revue Chemical Communications Année : 2020

Made-to-order porous electrodes for supercapacitors: MOFs embedded with redox-active centers as a case study

Résumé

In this work, a pre-designed Zr-based-MOF encompassing an organic linker with a redox active core is synthesized and its structureproperty relationship as a supercapacitor electrode is investigated. An enhanced performance is revealed by the combination of this MOF's high porosity and redox core incorporation, which alters its double-layer and pseudocapacitance, respectively. An increase in the capacitance performance by a factor of two is achieved via post-synthetic structure rigidification using organic pillars.

Domaines

Chimie
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Dates et versions

hal-03090535 , version 1 (29-12-2020)

Identifiants

Citer

Arijit Mallick, Hanfeng Liang, Osama Shekhah, Jiangtao Jia, Georges Mouchaham, et al.. Made-to-order porous electrodes for supercapacitors: MOFs embedded with redox-active centers as a case study. Chemical Communications, 2020, 56 (12), pp.1883-1886. ⟨10.1039/C9CC08860A⟩. ⟨hal-03090535⟩
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