Tethered oxocyclohexadienyl piano-stool Ru(II) complexes: a new class of metal-ligand bifunctional catalysts
Résumé
The straightforward synthesis of tethered η5-oxocyclohexadienyl metal complexes is presented. Preliminary studies in catalysis demonstrate that these tethered half-sandwich Ru(II) complexes behave as bifunctional catalysts with metal-ligand cooperativity and are promising candidates for the development of hydrogen-based energies and chemical storage (i.e. dissociated hydrogen).
Domaines
Chimie de coordination| Origine | Fichiers éditeurs autorisés sur une archive ouverte |
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