Article Dans Une Revue Organic Chemistry Frontiers Année : 2021

Electrochemical tandem trifluoromethylation of allylamines/formal (3 + 2)-cycloaddition for the rapid access to CF 3 -containing imidazolines and oxazolidines

Résumé

An electrochemical tandem radical trifluoromethylation of allylamines/formal (3+2)-cycloaddition with nitrile and carbonyl compounds has been developed under mild and environmentally benign reaction conditions. Such multicomponent reaction allowed the construction of CF 3-containing imidazolines and oxazolidines by creating three new bonds from simple and easily available starting materials.

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hal-03058541 , version 1 (15-12-2020)

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Aurélie Claraz, Aurélie Djian, Geraldine Masson. Electrochemical tandem trifluoromethylation of allylamines/formal (3 + 2)-cycloaddition for the rapid access to CF 3 -containing imidazolines and oxazolidines. Organic Chemistry Frontiers, 2021, 8, pp.288. ⟨10.1039/D0QO01307B⟩. ⟨hal-03058541⟩
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