Towards rare-earth-free white light-emitting diode devices based on the combination of dicyanomethylene and pyranine as organic dyes supported on zinc single-layered hydroxide - Archive ouverte HAL
Article Dans Une Revue Beilstein Journal of Nanotechnology Année : 2019

Towards rare-earth-free white light-emitting diode devices based on the combination of dicyanomethylene and pyranine as organic dyes supported on zinc single-layered hydroxide

Rachid Mahiou

Résumé

A new luminescent composite film resulting from the dispersion of luminescent organic dyes in a single-layered hydroxide (SLH)type inorganic matrix has been developed. Two fluorescent organic dyes emitting visible light upon blue LED excitation were investigated in this study: dicyanomethylene (DCM) and pyranine (HPTS). These dyes exhibit broad emission bands that cover a large part of the visible spectrum. The concept developed in our work consisted in keeping SLH in its wet form to ensure a good dispersion of the fluorescent dyes prior to immobilizing the hybrid materials in a silicone polymer to achieve luminescent composite films. We demonstrate that these coatings stacked upon each other and placed above a blue LED lead to white-light emission with suitable photometric parameters for applications in lighting or display devices: colour temperature of 5409 K and colour rendering index (CRI) of 81.
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Dates et versions

hal-03039769 , version 1 (04-12-2020)

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Rachid Mahiou. Towards rare-earth-free white light-emitting diode devices based on the combination of dicyanomethylene and pyranine as organic dyes supported on zinc single-layered hydroxide. Beilstein Journal of Nanotechnology, 2019, 10, pp.760-770. ⟨10.3762/bjnano.10.75⟩. ⟨hal-03039769⟩
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