Charge-driven interfacial gelation of cellulose nanofibrils across the water/oil interface
Résumé
Interfacial gels, obtained by the interaction of water-dispersible oxidised cellulose nanofibrils (OCNF) and oil-soluble oleylamine (OA), were produced across water/oil (W/O) interfaces. Surface rheology experiments showed that the complexation relies on the charge coupling between the negatively charged OCNF and OA. Complexation across the W/O interface was found to be dependent on the z-potential of the OCNF (modulated by electrolyte addition), leading to different interfacial properties. Spontaneous OCNF adsorption at the W/O interface occurred for particles with zeta-potential more negative than -30 mV, resulting in the formation of interfacial gels; whilst for particles with zeta-potential of ca. -30 mV, spontaneous adsorption occurred, coupled with augmented interfibrillar interactions, yielding stronger and tougher interfacial gels. On the contrary, charge neutralisation of OCNF (zeta-potential values more positive than -30 mV) did not allow spontaneous adsorption of OCNF at the W/O interface. In the case of favourable OCNF adsorption, the interfacial gel was found to embed oil-rich droplets – a spontaneous emulsification process.
Domaines
Chimie théorique et/ou physiqueOrigine | Publication financée par une institution |
---|