Journal Articles Angewandte Chemie International Edition Year : 2020

Effect of Hydrophilic Monomer Distribution on Self‐Assembly of a pH‐Responsive Copolymer: Spheres, Worms and Vesicles from a Single Copolymer Composition

Sylvain Prevost

Abstract

Copolymers of acrylic acid (AA) and butyl acrylate (BA) with constant overall composition (1:1 AA:BA) and controlled composition profiles (gradient, asymmetric diblock and asymmetric triblock) show dynamic pH-responsive self-assembly behavior, with reversible changes in size and formation of sphere, worm and vesicle morphologies, in contrast to the frozen micelles formed by poly(AA-block-BA) block copolymers.

Fichier principal
Vignette du fichier
Zhangetal.pdf (1.38 Mo) Télécharger le fichier
Origin Publisher files allowed on an open archive
Licence

Dates and versions

hal-03031355 , version 1 (16-11-2021)

Licence

Identifiers

Cite

Junliang Zhang, Barbara Farias‐mancilla, Ihor Kulai, Stephanie Hoeppener, Barbara Lonetti, et al.. Effect of Hydrophilic Monomer Distribution on Self‐Assembly of a pH‐Responsive Copolymer: Spheres, Worms and Vesicles from a Single Copolymer Composition. Angewandte Chemie International Edition, 2020, ⟨10.1002/anie.202010501⟩. ⟨hal-03031355⟩
148 View
179 Download

Altmetric

Share

  • More