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Article Dans Une Revue Journal of Chemistry Année : 2019

Cobalt-Salen Catalyzed Electroreductive Alkylation of Activated Olefins

Résumé

Cobalt-Salen mediated electroreductive and regioselective alkylation of electron deficient olefins is reported in one step in an undivided electrochemical cell, in the presence of an iron rod as sacrificial anode. Although the reactivity depends on the class of alkyl halides, the reported study offers a green and expeditious electrosynthetic route for Csp3-Csp3 bond formation in mild conditions. is study also confirms the possible formation of the heterobinuclear cobalt-Salen-iron complex previously reported as the effective catalyst.

Domaines

Chimie organique
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Dates et versions

hal-03021617 , version 1 (24-11-2020)

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Sylvie Condon, Céline Cannes, Fethi Bedioui. Cobalt-Salen Catalyzed Electroreductive Alkylation of Activated Olefins. Journal of Chemistry , 2019, 2019, pp.9832639. ⟨10.1155/2019/9832639⟩. ⟨hal-03021617⟩
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