Article Dans Une Revue Chemical Communications Année : 2020

A fluorous sodium l -prolinate derivative as low molecular weight gelator for perfluorocarbons

Bosi Mao
  • Fonction : Auteur
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  • IdRef : 201740923
Marc Schmutz

Résumé

We report the first study dealing with the self-assembly of an α-amino acid derivative in perfluorocarbons. Rheology, microscopy, and spectroscopy studies reveal that the fluorous sodium L-prolinate derivative 1 self-assembles in perfluorocarbons to form a three-dimensional network of left-handed nano-helices resulting in solvent gelation. Singlet oxygen lifetime measured in a gel of perfluorodecalin is about 1000 times longer than in pure water.

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hal-03016439 , version 1 (20-11-2020)

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Redouane Beniazza, Natalia Bayo, Damien Jardel, Ruben Rust, Bosi Mao, et al.. A fluorous sodium l -prolinate derivative as low molecular weight gelator for perfluorocarbons. Chemical Communications, 2020, 56 (61), pp.8655-8658. ⟨10.1039/d0cc02446e⟩. ⟨hal-03016439⟩
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