Chapitre D'ouvrage Année : 2020

N-heterocylic and mesoionic carbene complexes of the group 4 metals

Résumé

N-heterocyclic carbene (NHC) complexes of group 4 metals have been far less studied than their late metal counterparts. However, the field has been explored for over 25 years, and there is now a much clearer understanding of the metal-NHC interaction. Some exceptionally robust and active catalysts have been reported for a number of group 4 metal-catalyzed reactions, and recent developments suggest that NHCs are well-suited to enable the isolation of otherwise difficult to tame species, such as low-valent complexes.

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hal-02991504 , version 1 (06-11-2020)

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  • HAL Id : hal-02991504 , version 1

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Adrien T. Normand. N-heterocylic and mesoionic carbene complexes of the group 4 metals. Comprehensive Organometallic Chemistry IV, Gerard F. R. Parkin, Karsten Meyer, and Dermot O'Hare, editors. Section: Groups 3 to 4 and the f-elements, Stephen Liddle and David mills, section editors, In press. ⟨hal-02991504⟩
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