Match-mismatch effects in two-fold transfer of chirality within a Mobius metallo-receptor
Résumé
Two-fold transfer of chirality has been investigated in a Mobius Zn(ii) hexaphyrin metallo-receptor able to bind simultaneously two different chiral molecules. Match/mismatch effects influence the dynamic stereoselective twisting of the pi-system, and allow tuning of the induced chiroptical activity. Such allosteric control is attractive for building chirality sensing systems.
Domaines
Chimie
Fichier principal
Boitrel-2020-Match-Mismatch Effects in Twofold Transfer of Chirality within a Möbius Metallo-Receptor.pdf (921.02 Ko)
Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)
Loading...