Match-mismatch effects in two-fold transfer of chirality within a Mobius metallo-receptor - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Chemical Communications Année : 2020

Match-mismatch effects in two-fold transfer of chirality within a Mobius metallo-receptor

Résumé

Two-fold transfer of chirality has been investigated in a Mobius Zn(ii) hexaphyrin metallo-receptor able to bind simultaneously two different chiral molecules. Match/mismatch effects influence the dynamic stereoselective twisting of the pi-system, and allow tuning of the induced chiroptical activity. Such allosteric control is attractive for building chirality sensing systems.

Domaines

Chimie
Fichier principal
Vignette du fichier
Boitrel-2020-Match-Mismatch Effects in Twofold Transfer of Chirality within a Möbius Metallo-Receptor.pdf (921.02 Ko) Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)
Loading...

Dates et versions

hal-02928633 , version 1 (19-11-2020)

Identifiants

Citer

Bernard Boitrel, Stéphane Le Gac. Match-mismatch effects in two-fold transfer of chirality within a Mobius metallo-receptor. Chemical Communications, 2020, 56 (64), pp.9166-9169. ⟨10.1039/d0cc03877f⟩. ⟨hal-02928633⟩
79 Consultations
161 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More