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Article Dans Une Revue Synthesis: Journal of Synthetic Organic Chemistry Année : 2020

Formal [8+3]-Annulation between Azaoxyallyl Cations and Tropones

Résumé

For the first time, azaoxyallyl cations were used as cycloaddition partners with tropone derivatives to access nitrogen-containing [7,6]-fused bicycles in a metal-free process under mild reaction conditions. DFT computations have been used to shed light on the selectivities observed during the course of the reaction.

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Dates et versions

hal-02919117 , version 1 (18-11-2020)

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Guillaume Force, Amélie Pérot, Régis Guillot, Vincent Gandon, David Leboeuf. Formal [8+3]-Annulation between Azaoxyallyl Cations and Tropones. Synthesis: Journal of Synthetic Organic Chemistry, 2020, 52 (04), pp.553-564. ⟨10.1055/s-0039-1690745⟩. ⟨hal-02919117⟩
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