rac -{[2-(Diphenylthiophosphanyl)ferrocenyl]methyl}trimethylammonium iodide chloroform monosolvate - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Acta Crystallographica Section E : Structure Reports Online [2001-2014] Année : 2012

rac -{[2-(Diphenylthiophosphanyl)ferrocenyl]methyl}trimethylammonium iodide chloroform monosolvate

Résumé

The title compound, [Fe(C5H5)(C21H24NPS)]I·CHCl3, is built up from a (ferrocenylmeth­yl)trimethyl­ammonium cation, a iodine anion and a chloro­form solvent mol­ecule, all residing in general positions. The N atom of the ammonium group is displaced by 1.182 (2) Å from the plane of the substituted cyclo­penta­dienyl (Cp) ring towards the Fe atom, whereas the C atom attached to the same Cp ring is slightly below this plane by -0.128 (2) Å. These deviations might result from weak agostic interactions between the two H atoms of the CH2 group and the Fe atom

Dates et versions

hal-02909976 , version 1 (31-07-2020)

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Citer

Andrii Karpus, Zoia Voitenko, Jean-Claude Daran, Eric Manoury. rac -{[2-(Diphenylthiophosphanyl)ferrocenyl]methyl}trimethylammonium iodide chloroform monosolvate. Acta Crystallographica Section E : Structure Reports Online [2001-2014], 2012, 68 (12), pp.m1490-m1491. ⟨10.1107/S1600536812046053⟩. ⟨hal-02909976⟩
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