Taming the Reactivity of Phosphiranium Salts: Site‐Selective C‐Centered Ring Opening for Direct Synthesis of Phosphinoethylamines - Archive ouverte HAL Access content directly
Journal Articles Angewandte Chemie International Edition Year : 2020

Taming the Reactivity of Phosphiranium Salts: Site‐Selective C‐Centered Ring Opening for Direct Synthesis of Phosphinoethylamines

Abstract

Advances in the field of phosphorus chemistry are documented, by revealing the synthetic utility of previously underutilized quaternary phosphiranium salts (QPrS) as three-chain-atom electrophilic building blocks. Notably, control of their challenging C-centered electrophilicity is disclosed with an expedient synthesis of tertiary beta-anilino phosphines as a proof-of-concept.
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hal-02899688 , version 1 (15-12-2020)

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Julien Gasnot, Clément Botella, Sébastien Comesse, Sami Lakhdar, Carole Alayrac, et al.. Taming the Reactivity of Phosphiranium Salts: Site‐Selective C‐Centered Ring Opening for Direct Synthesis of Phosphinoethylamines. Angewandte Chemie International Edition, 2020, 59 (29), pp.11769-11773. ⟨10.1002/anie.201916449⟩. ⟨hal-02899688⟩
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