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Article Dans Une Revue Organometallics Année : 2012

Elegant Approach to the Synthesis of a Unique Heteroleptic Cyclometalated Iridium(III)-Polyoxometalate Conjugate

Résumé

A novel heteroleptic cyclometalated iridium(III) complex with one picolinic acid derivative bearing a pendant terminal alkynyl tether has been prepared following a new synthetic route. This pendant alkynyl tether can be further engaged in palladium C?C coupling reactions, allowing its grafting to a Keggin-type polyoxometalate and thus providing a unique iridio-POM conjugate.

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Chimie
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Dates et versions

hal-02878863 , version 1 (23-06-2020)

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Benjamin Matt, Jamal Moussa, Lise-Marie Chamoreau, Carlos Afonso, Anna Proust, et al.. Elegant Approach to the Synthesis of a Unique Heteroleptic Cyclometalated Iridium(III)-Polyoxometalate Conjugate. Organometallics, 2012, 31 (1), pp.35--38. ⟨10.1021/om200910p⟩. ⟨hal-02878863⟩
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