Adsorption and corrosion inhibition properties of 5-amino 1,3,4-thiadiazole-2-thiol on the mild steel in hydrochloric acid medium: Thermodynamic, surface and electrochemical studies - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Journal of Electroanalytical Chemistry Année : 2017

Adsorption and corrosion inhibition properties of 5-amino 1,3,4-thiadiazole-2-thiol on the mild steel in hydrochloric acid medium: Thermodynamic, surface and electrochemical studies

Résumé

The inhibition effect of 5-amino 1,3,4-thiadiazole-2-thiol (5-ATT) on the corrosion of mild steel in 1 M HCl solution at 303 K was studied practicing weight loss, electrochemical electrochemical (AC and DC) studies and Xray photoelectron spectroscopy (XPS) methods. The obtained results showed that 5-ATT was an effective inhibitor in HCl medium. The inhibition efficiency, eta(%), increased with the increase in concentration inhibitor but the temperature has almost no effect on the inhibition efficiency of 5-ATT. The activation dissolution thermodynamic parameters were calculated and discussed. Thermodynamic data and XPS analysis clearly show that the adsorption mechanism of 5-ATT on the mild steel surface in 1 M HCl solution is mainly electrostatic-adsorption. Tafel curves reveal that 5-ATT behaves as a mixed-type inhibitor with cathodic predominance and obeyed Langmuir adsorption isotherm. With the aim of extracting the parameters of the electrochemical impedance spectroscopy an appropriate equivalent circuit model was offered.
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Dates et versions

hal-02619688 , version 1 (25-05-2020)

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Houari Ouici, M Tourabi, O. Benali, C. Selles, Charafeddine Jama, et al.. Adsorption and corrosion inhibition properties of 5-amino 1,3,4-thiadiazole-2-thiol on the mild steel in hydrochloric acid medium: Thermodynamic, surface and electrochemical studies. Journal of Electroanalytical Chemistry, 2017, 803, pp.125-134. ⟨10.1016/j.jelechem.2017.09.018⟩. ⟨hal-02619688⟩

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