Reaction of Methyllithium with Group 6 Phosphine Dinitrogen Complexes
Résumé
The reaction of MeLi with several group 6 phosphine end-on dinitrogen complexes of the general formula [ML4(N2)2] (M = Mo or W) is reported. Unlike the isoelectronic complex [CpMn(CO)2(N2)] on which RLi reagents have been reported to add to the N2 ligand, we show herein that MeLi attacks the metal centre to afford rare anionic trans methyl dinitrogen complexes.
Domaines
Chimie de coordination| Origine | Fichiers produits par l'(les) auteur(s) |
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