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Article Dans Une Revue Dalton Transactions Année : 2019

Complete post-synthetic modification of a spin crossover complex

Résumé

The post-synthetic reaction between p-anisaldehyde and the spin-crossover compd. [Fe(NH2-trz)3](NO3)2 (NH2-trz = 4-amino-1,2,4-triazole) was explored, obtaining different degrees of transformation from 23% to full conversion by varying the reaction time. The post-synthetic SCO complexes obtained were studied by magnetometry, powder x-ray diffraction (PXRD), elemental anal., solid state NMR and IR and compared with the corresponding compds. obtained by direct synthetic routes, revealing new spin crossover properties.
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Dates et versions

hal-02570013 , version 1 (23-11-2020)

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Alejandro Enriquez-Cabrera, Lucie Routaboul, Lionel Salmon, Azzedine Bousseksou. Complete post-synthetic modification of a spin crossover complex. Dalton Transactions, 2019, 48 (45), pp.16853-16856. ⟨10.1039/c9dt03587g⟩. ⟨hal-02570013⟩
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