<?xml version="1.0" encoding="utf-8"?>
<TEI xmlns="http://www.tei-c.org/ns/1.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:hal="http://hal.archives-ouvertes.fr/" xmlns:gml="http://www.opengis.net/gml/3.3/" xmlns:gmlce="http://www.opengis.net/gml/3.3/ce" version="1.1" xsi:schemaLocation="http://www.tei-c.org/ns/1.0 http://api.archives-ouvertes.fr/documents/aofr-sword.xsd">
  <teiHeader>
    <fileDesc>
      <titleStmt>
        <title>HAL TEI export of hal-02549258</title>
      </titleStmt>
      <publicationStmt>
        <distributor>CCSD</distributor>
        <availability status="restricted">
          <licence target="https://creativecommons.org/publicdomain/zero/1.0/">CC0 1.0 - Universal</licence>
        </availability>
        <date when="2026-05-18T19:55:28+02:00"/>
      </publicationStmt>
      <sourceDesc>
        <p part="N">HAL API Platform</p>
      </sourceDesc>
    </fileDesc>
  </teiHeader>
  <text>
    <body>
      <listBibl>
        <biblFull>
          <titleStmt>
            <title xml:lang="en">Impact of aluminum on the structure of geopolymers from the early stages to consolidated material</title>
            <author role="aut">
              <persName>
                <forename type="first">Virginie</forename>
                <surname>Benavent</surname>
              </persName>
              <idno type="halauthorid">1731837-0</idno>
              <affiliation ref="#struct-92792"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Prune</forename>
                <surname>Steins</surname>
              </persName>
              <idno type="halauthorid">849844-0</idno>
              <affiliation ref="#struct-40054"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Isabel</forename>
                <surname>Sobrados</surname>
              </persName>
              <idno type="halauthorid">137839-0</idno>
              <affiliation ref="#struct-503385"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Jesus</forename>
                <surname>Sanz</surname>
              </persName>
              <idno type="halauthorid">778154-0</idno>
              <affiliation ref="#struct-11108"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">David</forename>
                <surname>Lambertin</surname>
              </persName>
              <idno type="halauthorid">819638-0</idno>
              <affiliation ref="#struct-40055"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Fabien</forename>
                <surname>Frizon</surname>
              </persName>
              <idno type="halauthorid">646396-0</idno>
              <affiliation ref="#struct-40067"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">S.</forename>
                <surname>Rossignol</surname>
              </persName>
              <email type="md5">8408ae32ea65aa873e24a49210a23920</email>
              <email type="domain">univ-amu.fr</email>
              <idno type="idhal" notation="string">stephanie-rossignol</idno>
              <idno type="idhal" notation="numeric">13147</idno>
              <idno type="halauthorid" notation="string">34671-13147</idno>
              <idno type="ORCID">https://orcid.org/0000-0001-8127-6604</idno>
              <idno type="IDREF">https://www.idref.fr/169090221</idno>
              <affiliation ref="#struct-389672"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Arnaud</forename>
                <surname>Poulesquen</surname>
              </persName>
              <email type="md5">1e4c6dcafaaff1e1c9840445cda20545</email>
              <email type="domain">cea.fr</email>
              <idno type="idhal" notation="string">arnaud-poulesquen</idno>
              <idno type="idhal" notation="numeric">1424579</idno>
              <idno type="halauthorid" notation="string">434803-1424579</idno>
              <idno type="ORCID">https://orcid.org/0000-0003-1725-3912</idno>
              <affiliation ref="#struct-40055"/>
            </author>
            <editor role="depositor">
              <persName>
                <forename>BEATRICE</forename>
                <surname>DERORY</surname>
              </persName>
              <email type="md5">c540878259a2fe2a62e9bcb81023a46c</email>
              <email type="domain">unilim.fr</email>
            </editor>
          </titleStmt>
          <editionStmt>
            <edition n="v1" type="current">
              <date type="whenSubmitted">2020-04-21 12:23:12</date>
              <date type="whenModified">2024-11-28 03:39:15</date>
              <date type="whenReleased">2020-04-21 12:23:12</date>
              <date type="whenProduced">2016-12</date>
            </edition>
            <respStmt>
              <resp>contributor</resp>
              <name key="630707">
                <persName>
                  <forename>BEATRICE</forename>
                  <surname>DERORY</surname>
                </persName>
                <email type="md5">c540878259a2fe2a62e9bcb81023a46c</email>
                <email type="domain">unilim.fr</email>
              </name>
            </respStmt>
          </editionStmt>
          <publicationStmt>
            <distributor>CCSD</distributor>
            <idno type="halId">hal-02549258</idno>
            <idno type="halUri">https://unilim.hal.science/hal-02549258</idno>
            <idno type="halBibtex">benavent:hal-02549258</idno>
            <idno type="halRefHtml">&lt;i&gt;Cement and Concrete Research&lt;/i&gt;, 2016, 90, pp.27-35. &lt;a target="_blank" href="https://dx.doi.org/10.1016/j.cemconres.2016.09.009"&gt;&amp;#x27E8;10.1016/j.cemconres.2016.09.009&amp;#x27E9;&lt;/a&gt;</idno>
            <idno type="halRef">Cement and Concrete Research, 2016, 90, pp.27-35. &amp;#x27E8;10.1016/j.cemconres.2016.09.009&amp;#x27E9;</idno>
            <availability status="restricted"/>
          </publicationStmt>
          <seriesStmt>
            <idno type="stamp" n="CEA">CEA - Commissariat à l'énergie atomique</idno>
            <idno type="stamp" n="UNILIM">Université de Limoges</idno>
            <idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno>
            <idno type="stamp" n="SPCTS" corresp="UNILIM">Science des Procédés Céramiques et de Traitements de Surface</idno>
            <idno type="stamp" n="SPCTS-AXE3" corresp="SPCTS">Axe 3 : organisation structurale multiéchelle des matériaux</idno>
            <idno type="stamp" n="IPAM" corresp="UNILIM">Institut des Procédés Appliqués aux Matériaux</idno>
            <idno type="stamp" n="DEN" corresp="CEA">Direction des énergies</idno>
            <idno type="stamp" n="INC-CNRS">Institut de Chimie du CNRS</idno>
            <idno type="stamp" n="IRCER" corresp="UNILIM">Institut de Recherche sur les CERamiques</idno>
            <idno type="stamp" n="IRCER-AXE3" corresp="IRCER">IRCER - Axe 3 : organisation structurale multiéchelle des matériaux</idno>
            <idno type="stamp" n="DEN-MARCO" corresp="CEA">DES Marcoule</idno>
            <idno type="stamp" n="IMPEO" corresp="UNILIM">Institut Matériaux Procédés Environnement Ouvrages</idno>
            <idno type="stamp" n="TEST2-HALCNRS">TEST2-HALCNRS</idno>
            <idno type="stamp" n="ISEC" corresp="DEN">l’Institut des sciences et technologies pour une économie circulaire des énergies bas carbone (ISEC)</idno>
          </seriesStmt>
          <notesStmt>
            <note type="audience" n="2">International</note>
            <note type="popular" n="0">No</note>
            <note type="peer" n="1">Yes</note>
          </notesStmt>
          <sourceDesc>
            <biblStruct>
              <analytic>
                <title xml:lang="en">Impact of aluminum on the structure of geopolymers from the early stages to consolidated material</title>
                <author role="aut">
                  <persName>
                    <forename type="first">Virginie</forename>
                    <surname>Benavent</surname>
                  </persName>
                  <idno type="halauthorid">1731837-0</idno>
                  <affiliation ref="#struct-92792"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Prune</forename>
                    <surname>Steins</surname>
                  </persName>
                  <idno type="halauthorid">849844-0</idno>
                  <affiliation ref="#struct-40054"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Isabel</forename>
                    <surname>Sobrados</surname>
                  </persName>
                  <idno type="halauthorid">137839-0</idno>
                  <affiliation ref="#struct-503385"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Jesus</forename>
                    <surname>Sanz</surname>
                  </persName>
                  <idno type="halauthorid">778154-0</idno>
                  <affiliation ref="#struct-11108"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">David</forename>
                    <surname>Lambertin</surname>
                  </persName>
                  <idno type="halauthorid">819638-0</idno>
                  <affiliation ref="#struct-40055"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Fabien</forename>
                    <surname>Frizon</surname>
                  </persName>
                  <idno type="halauthorid">646396-0</idno>
                  <affiliation ref="#struct-40067"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">S.</forename>
                    <surname>Rossignol</surname>
                  </persName>
                  <email type="md5">8408ae32ea65aa873e24a49210a23920</email>
                  <email type="domain">univ-amu.fr</email>
                  <idno type="idhal" notation="string">stephanie-rossignol</idno>
                  <idno type="idhal" notation="numeric">13147</idno>
                  <idno type="halauthorid" notation="string">34671-13147</idno>
                  <idno type="ORCID">https://orcid.org/0000-0001-8127-6604</idno>
                  <idno type="IDREF">https://www.idref.fr/169090221</idno>
                  <affiliation ref="#struct-389672"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Arnaud</forename>
                    <surname>Poulesquen</surname>
                  </persName>
                  <email type="md5">1e4c6dcafaaff1e1c9840445cda20545</email>
                  <email type="domain">cea.fr</email>
                  <idno type="idhal" notation="string">arnaud-poulesquen</idno>
                  <idno type="idhal" notation="numeric">1424579</idno>
                  <idno type="halauthorid" notation="string">434803-1424579</idno>
                  <idno type="ORCID">https://orcid.org/0000-0003-1725-3912</idno>
                  <affiliation ref="#struct-40055"/>
                </author>
              </analytic>
              <monogr>
                <idno type="halJournalId" status="VALID">11576</idno>
                <idno type="issn">0008-8846</idno>
                <title level="j">Cement and Concrete Research</title>
                <imprint>
                  <publisher>Elsevier</publisher>
                  <biblScope unit="volume">90</biblScope>
                  <biblScope unit="pp">27-35</biblScope>
                  <date type="datePub">2016-12</date>
                </imprint>
              </monogr>
              <idno type="doi">10.1016/j.cemconres.2016.09.009</idno>
            </biblStruct>
          </sourceDesc>
          <profileDesc>
            <langUsage>
              <language ident="en">English</language>
            </langUsage>
            <textClass>
              <classCode scheme="halDomain" n="chim.mate">Chemical Sciences/Material chemistry</classCode>
              <classCode scheme="halDomain" n="spi.mat">Engineering Sciences [physics]/Materials</classCode>
              <classCode scheme="halTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halOldTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halTreeTypology" n="ART">Journal articles</classCode>
            </textClass>
            <abstract xml:lang="en">
              <p>The aim of this study is to assess the effects of the addition of aluminum (NaAlO2) into the activating solution on the geopolymerization reactions and the characteristics of the porous network. It was established by liquid state NMR that the speciation of the aluminosilicate oligomers and then the mean degree of polymerization were modified by the addition of sodium aluminate in the activating solution. Time-resolved SAXS and rheology results on geopolymer pastes showed that the molar ratios Si/Al and (Si + Al)/Na2O in the activating solution play a major role in the geopolymer properties at liquid and solid state. Indeed, the geopolymer percolating network appeared sooner and the properties of the porous network were dramatically changed with the addition of the NaAlO2. On the other hand, two geopolymers having identical final chemical composition but a different activating solution composition, showed to the same setting time and the same porous network characteristics.</p>
            </abstract>
          </profileDesc>
        </biblFull>
      </listBibl>
    </body>
    <back>
      <listOrg type="structures">
        <org type="regrouplaboratory" xml:id="struct-92792" status="VALID">
          <idno type="IdRef">134643534</idno>
          <idno type="ISNI">0000000121804137</idno>
          <idno type="RNSR">200018571R</idno>
          <idno type="ROR">https://ror.org/03cwzta72</idno>
          <idno type="Wikidata"> Q30299415</idno>
          <orgName>CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire)</orgName>
          <orgName type="acronym">CEA-DES (ex-DEN)</orgName>
          <desc>
            <address>
              <country key="FR"/>
            </address>
          </desc>
          <listRelation>
            <relation name="DES" active="#struct-300016" type="direct"/>
          </listRelation>
        </org>
        <org type="department" xml:id="struct-40054" status="OLD">
          <orgName>Département d'études du Traitement et du Conditionnement des Déchets</orgName>
          <orgName type="acronym">DTCD</orgName>
          <date type="end">2017-01-01</date>
          <desc>
            <address>
              <addrLine>CEA Marcoule, BP 17171, 30207 Bagnols-sur-Ceze Cedex</addrLine>
              <country key="FR"/>
            </address>
          </desc>
          <listRelation>
            <relation name="DEN/DTCD" active="#struct-92792" type="direct"/>
            <relation name="DES" active="#struct-300016" type="indirect"/>
          </listRelation>
        </org>
        <org type="regrouplaboratory" xml:id="struct-503385" status="VALID">
          <orgName>Instituto de Ciencia de Materiales de Madrid</orgName>
          <orgName type="acronym">ICMM</orgName>
          <desc>
            <address>
              <addrLine>Calle Sor Juana Inés de la Cruz, 3, 28049 Madrid, Espagne</addrLine>
              <country key="ES"/>
            </address>
            <ref type="url">https://www.icmm.csic.es</ref>
          </desc>
          <listRelation>
            <relation active="#struct-106380" type="direct"/>
          </listRelation>
        </org>
        <org type="regrouplaboratory" xml:id="struct-11108" status="VALID">
          <orgName>Instituto de Ciencia de Materiales de Aragón [Saragoza, España]</orgName>
          <orgName type="acronym">ICMA-CSIC</orgName>
          <desc>
            <address>
              <addrLine>E-50009 Zaragoza</addrLine>
              <country key="ES"/>
            </address>
          </desc>
          <listRelation>
            <relation active="#struct-95355" type="direct"/>
          </listRelation>
        </org>
        <org type="researchteam" xml:id="struct-40055" status="OLD">
          <orgName>Laboratoire d'Etudes de l'Enrobage des Déchets</orgName>
          <orgName type="acronym">L2ED</orgName>
          <desc>
            <address>
              <country key="FR"/>
            </address>
          </desc>
          <listRelation>
            <relation active="#struct-40067" type="direct"/>
            <relation active="#struct-92792" type="indirect"/>
            <relation name="DES" active="#struct-300016" type="indirect"/>
          </listRelation>
        </org>
        <org type="laboratory" xml:id="struct-40067" status="OLD">
          <orgName>Service des Procedés de Décontamination et d'Enrobage des Déchets</orgName>
          <orgName type="acronym">SPDE</orgName>
          <desc>
            <address>
              <country key="FR"/>
            </address>
          </desc>
          <listRelation>
            <relation active="#struct-92792" type="direct"/>
            <relation name="DES" active="#struct-300016" type="indirect"/>
          </listRelation>
        </org>
        <org type="researchteam" xml:id="struct-389672" status="OLD">
          <orgName>Axe 3 : organisation structurale multiéchelle des matériaux</orgName>
          <orgName type="acronym">SPCTS-AXE3</orgName>
          <date type="start">2012-01-01</date>
          <date type="end">2017-12-31</date>
          <desc>
            <address>
              <country key="FR"/>
            </address>
          </desc>
          <listRelation>
            <relation active="#struct-179082" type="direct"/>
            <relation name="UMR7315" active="#struct-5928" type="indirect"/>
            <relation name="UMR7315" active="#struct-300398" type="indirect"/>
            <relation name="UMR7315" active="#struct-301999" type="indirect"/>
            <relation active="#struct-5928" type="indirect"/>
            <relation name="UMR7315" active="#struct-341038" type="indirect"/>
            <relation name="UMR7315" active="#struct-441569" type="indirect"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-300016" status="VALID">
          <idno type="IdRef">026372061</idno>
          <idno type="ISNI">0000000122998025</idno>
          <idno type="ROR">https://ror.org/00jjx8s55</idno>
          <idno type="Wikidata">Q868550</idno>
          <orgName>Commissariat à l'énergie atomique et aux énergies alternatives</orgName>
          <orgName type="acronym">CEA</orgName>
          <desc>
            <address>
              <addrLine>Centre de SaclayCentre de GrenobleCentre de Cadaracheetc</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.cea.fr/</ref>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-106380" status="VALID">
          <idno type="IdRef">026373246</idno>
          <idno type="ISNI">0000000123535612</idno>
          <idno type="ROR">https://ror.org/02gfc7t72</idno>
          <idno type="Wikidata">Q74202089</idno>
          <orgName>Consejo Superior de Investigaciones Cientificas [España] = Spanish National Research Council [Spain]</orgName>
          <orgName type="acronym">CSIC</orgName>
          <date type="start">1939-01-01</date>
          <desc>
            <address>
              <addrLine>Serrano 117, 28006, Madrid</addrLine>
              <country key="ES"/>
            </address>
            <ref type="url">http://www.csic.es/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-95355" status="VALID">
          <idno type="IdRef">028039343</idno>
          <idno type="ISNI">0000000121528769</idno>
          <idno type="ROR">https://ror.org/012a91z28</idno>
          <idno type="Wikidata">Q633561</idno>
          <orgName>Universidad de Zaragoza = University of Zaragoza [Saragossa University] = Université de Saragosse</orgName>
          <date type="start">1542-01-01</date>
          <desc>
            <address>
              <addrLine>Pedro Cerbuna,12 – 50009 Zaragoza – España</addrLine>
              <country key="ES"/>
            </address>
            <ref type="url">http://www.unizar.es/</ref>
          </desc>
        </org>
        <org type="laboratory" xml:id="struct-179082" status="OLD">
          <idno type="IdRef">171538005</idno>
          <idno type="ISNI">0000000404524960 </idno>
          <idno type="RNSR">201220198G</idno>
          <idno type="ROR">https://ror.org/044qpwz88</idno>
          <orgName>Science des Procédés Céramiques et de Traitements de Surface</orgName>
          <orgName type="acronym">SPCTS</orgName>
          <date type="start">2012-01-01</date>
          <date type="end">2017-12-31</date>
          <desc>
            <address>
              <addrLine>SPCTS, Centre Européen de la Céramique, 12 Rue Atlantis, 87068 LIMOGES CEDEX</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.unilim.fr/spcts/</ref>
          </desc>
          <listRelation>
            <relation name="UMR7315" active="#struct-5928" type="direct"/>
            <relation name="UMR7315" active="#struct-300398" type="direct"/>
            <relation name="UMR7315" active="#struct-301999" type="direct"/>
            <relation active="#struct-5928" type="direct"/>
            <relation name="UMR7315" active="#struct-341038" type="direct"/>
            <relation name="UMR7315" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-5928" status="VALID">
          <idno type="IdRef">026403315</idno>
          <idno type="ISNI">0000000121654861</idno>
          <idno type="ROR">https://ror.org/02cp04407</idno>
          <orgName>Université de Limoges</orgName>
          <orgName type="acronym">UNILIM</orgName>
          <date type="start">1968-10-01</date>
          <desc>
            <address>
              <addrLine>33 rue François Mitterrand BP23204 87032 Limoges</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.unilim.fr</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-300398" status="OLD">
          <idno type="IdRef">055339174</idno>
          <idno type="ROR">https://ror.org/00ysecr35</idno>
          <orgName>Ecole Nationale Supérieure de Céramique Industrielle</orgName>
          <orgName type="acronym">ENSCI</orgName>
          <date type="start">1955-01-01</date>
          <date type="end">2017-01-01</date>
          <desc>
            <address>
              <addrLine>Centre Européen de la Céramique - 12, rue Atlantis - 87068 Limoges Cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.ensci.fr/</ref>
          </desc>
        </org>
        <org type="regrouplaboratory" xml:id="struct-301999" status="VALID">
          <idno type="IdRef">144784513</idno>
          <orgName>Institut des Procédés Appliqués aux Matériaux</orgName>
          <orgName type="acronym">IPAM</orgName>
          <date type="end">2021-12-31</date>
          <desc>
            <address>
              <addrLine>Centre Européen de la Céramique12, rue Atlantis, parc d’Ester87068 Limoges Cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.unilim.fr/recherche/laboratoires/ipam/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-5928" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-341038" status="VALID">
          <idno type="IdRef">232435103</idno>
          <idno type="ISNI">000000010626358X</idno>
          <idno type="ROR">https://ror.org/02cte4b68</idno>
          <orgName>Institut de Chimie - CNRS Chimie</orgName>
          <orgName type="acronym">INC-CNRS</orgName>
          <date type="start">2009-10-01</date>
          <desc>
            <address>
              <addrLine>CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE3 rue Michel-Ange75794 PARIS CEDEX 16 - France</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.cnrs.fr/inc</ref>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-441569" status="VALID">
          <idno type="IdRef">02636817X</idno>
          <idno type="ISNI">0000000122597504</idno>
          <idno type="ROR">https://ror.org/02feahw73</idno>
          <orgName>Centre National de la Recherche Scientifique</orgName>
          <orgName type="acronym">CNRS</orgName>
          <date type="start">1939-10-19</date>
          <desc>
            <address>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.cnrs.fr/</ref>
          </desc>
        </org>
      </listOrg>
    </back>
  </text>
</TEI>