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Article Dans Une Revue Journal of Analytical and Applied Pyrolysis Année : 2018

Thermal cracking of n -butylbenzene at high pressure: Experimental study and kinetic modelling

Résumé

Highlights  Pyrolysis of n-butylbenzene at 70 MPa and from 583 K to 623 K was performed in sealed gold tubes.  The main products are toluene, ethylbenzene, iso-heptyl-and iso-butylbenzene, CH4 and C2H6.  A detailed kinetic model was constructed and validated over the entire experimental range of conversion (0.7-62%).  Thermochemical and kinetic parameters of key decomposition routes were computed using theoretical calculations.
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hal-02370755 , version 1 (19-11-2019)

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N.C. C Leguizamon Guerra, J.C. C Lizardo Huerta, C. Lorgeoux, R. Michels, R. Fournet, et al.. Thermal cracking of n -butylbenzene at high pressure: Experimental study and kinetic modelling. Journal of Analytical and Applied Pyrolysis, 2018, 133, pp.234-245. ⟨10.1016/j.jaap.2018.03.016⟩. ⟨hal-02370755⟩
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