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              <p>[87985-40-8] C8H16N4O4Rh2 (MW 438.10)InChI = 1S/4C2H5NO.2Rh/c4*1-2(3)4;;/h4*1H3,(H2,3,4);;/q;;;;2*+2/p-4InChIKey = VKOXSPVYCVPFMU-UHFFFAOYSA-J(catalyst for selective carbenoid reactions of diazo compounds1)Alternate Name: dirhodium(II) tetraacetamidate.Physical Data: UV/vis (MeCN) 500 (2.2), 345 (shoulder) nm.2 NMR (CD3CN): δ 2.20 (s).3Spectral Data: λ 500, 345 (shoulder) nm (CH3CN).2 1H NMR (CD3CN) of Rh2(acam)4-(CH3CN)2: δ 2.20 (s, 12 H).Solubility: sol MeOH, MeCN, pyridine, DMSO; insol CH2Cl2, ClCH2CH2Cl, toluene.Form Supplied in: blue solid for anhydrous form and after removal of axial nitrile ligands; purple solid as hydrate and as the bisacetonitrile complex.Preparative Method: from dirhodium tetraacetate by ligand substitution with acetamide (eq 1).3</p>
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