Field theory for ionic systems. From fluctuations and structure at a hard wall to thermodynamics - Archive ouverte HAL
Article Dans Une Revue Electrochimica Acta Année : 2003

Field theory for ionic systems. From fluctuations and structure at a hard wall to thermodynamics

Résumé

We use a field theoretical approach to study ionic systems. In this paper we illustrate this formalism in a grand canonical ensemble for the long range Coulomb potential. For the inhomogeneous system near a hard neutral plane wall we go beyond the well known Debye–Hückel electrolyte results and predict the existence of a desorption profile. The results are compared with well established sum rules for ionic systems and thermodynamic relations are verified. We also calculate the differential capacitance in a slab using the linear response theory. The capacitance is calculated from the charge–charge correlations for the neutral system using the fluctuation–dissipation theorem.
Fichier principal
Vignette du fichier
paper.pdf (298.51 Ko) Télécharger le fichier
Origine Fichiers produits par l'(les) auteur(s)
Licence

Dates et versions

hal-02354770 , version 1 (20-10-2023)

Licence

Identifiants

Citer

Dung Di Caprio, J. Stafiej, J.P. Badiali. Field theory for ionic systems. From fluctuations and structure at a hard wall to thermodynamics. Electrochimica Acta, 2003, 48 (20-22), pp.2967-2974. ⟨10.1016/S0013-4686(03)00362-1⟩. ⟨hal-02354770⟩
20 Consultations
21 Téléchargements

Altmetric

Partager

More