A3-Coupling Reaction and [Ag(IPr)2]PF6: A Successful Couple

Homoleptic and cationic [Ag(IPr)2]PF6 [IPr = 1,3‐bis(2,6‐diisopropylphenyl)imidazolylidene] is an efficient catalyst for the A3‐coupling reaction. Propargylamines are synthesized in short reaction times with low catalyst loadings under microwave irradiation or continuous flow. This approach is user friendly, versatile, and compatible with both aliphatic and aromatic aldehydes and alkynes.

Mots clés

Silver complexes NHC ligands N-heterocyclic carbene catalysis A3 coupling flow chemistry propargyl amines

Domaines

Chimie de coordination Catalyse Chimie organique

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Hal-120-2017.pdf (1.52 Mo)

Origine	Fichiers produits par l'(les) auteur(s)

Thomas-Xavier Métro : Connectez-vous pour contacter le contributeur

https://hal.science/hal-02338923

Soumis le : vendredi 29 janvier 2021-12:06:19

Dernière modification le : mardi 7 mai 2024-08:28:30

Dates et versions

hal-02338923 , version 1 (29-01-2021)

Identifiants

HAL Id : hal-02338923 , version 1
DOI : 10.1002/ejoc.201700985

Citer

Audrey Beillard, Thomas-Xavier Métro, Xavier Bantreil, Jean Martinez, Frédéric Lamaty. A3-Coupling Reaction and [Ag(IPr)2]PF6: A Successful Couple. European Journal of Organic Chemistry, 2017, 2017 (31), pp.4642-4647. ⟨10.1002/ejoc.201700985⟩. ⟨hal-02338923⟩

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