Encapsulation of Chaotropic closo -Decahydrodecaborate Clusters Within Cyclodextrins: Synthesis, Solution Studies, and DFT Calculations
Résumé
This paper deals with the formation of host-guest systems between cyclodextrins and the closo-decahydrodecaborate cluster. The inclusion processes, although involving weak interaction, were evidenced in solution by ESI-MS and various NMR techniques. ITC measurements provided thermodynamic parameters and DFT calculation gave some elements allowing understanding these processes.
Domaines
Chimie| Origine | Fichiers produits par l'(les) auteur(s) |
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