Encapsulation of Chaotropic closo -Decahydrodecaborate Clusters Within Cyclodextrins: Synthesis, Solution Studies, and DFT Calculations - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue European Journal of Inorganic Chemistry Année : 2019

Encapsulation of Chaotropic closo -Decahydrodecaborate Clusters Within Cyclodextrins: Synthesis, Solution Studies, and DFT Calculations

Résumé

This paper deals with the formation of host-guest systems between cyclodextrins and the closo-decahydrodecaborate cluster. The inclusion processes, although involving weak interaction, were evidenced in solution by ESI-MS and various NMR techniques. ITC measurements provided thermodynamic parameters and DFT calculation gave some elements allowing understanding these processes.

Domaines

Chimie
Fichier principal
Vignette du fichier
B10 CD second revision_final.pdf (3.5 Mo) Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)

Dates et versions

hal-02335711 , version 1 (10-01-2021)

Identifiants

Citer

Manal Diab, Sébastien Floquet, Mohamed Haouas, Pavel Abramov, Xavier López, et al.. Encapsulation of Chaotropic closo -Decahydrodecaborate Clusters Within Cyclodextrins: Synthesis, Solution Studies, and DFT Calculations. European Journal of Inorganic Chemistry, 2019, 2019 (29), pp.3373-3382. ⟨10.1002/ejic.201900602⟩. ⟨hal-02335711⟩
41 Consultations
106 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More