Aqueous Ring-Opening Polymerization-Induced Self-Assembly (ROPISA) of N-carboxyanhydrides
Résumé
We report the first aqueous ring‐opening polymerization (ROP) of N‐carboxyanhydrides (NCA) using α‐amino‐poly(ethylene oxide) macroinitiator to protect NCA monomers from hydrolysis through spontaneous in situ self‐assembly (ISA). This ROPISA process affords well‐defined amphiphilic diblock copolymers that simultaneously form original needle‐like nano‐objects.
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