A cyanide and hydroxo-bridged nanocage: a new generation of coordination clusters
Résumé
Combining serendipitously-formed hydroxo-clusters, [CoII3(OH)(piv)4(L)]+ (where L = MeCN or Hpiv), with assembling cyanide building block, [FeIII(Tp)(CN)3]−, has led to an unprecedented architecture where polymetallic cobalt clusters and blocked tris-cyanide iron complexes define the apexes of a unique magnetic cubic nanocage.
Domaines
Chimie de coordinationOrigine | Fichiers produits par l'(les) auteur(s) |
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