Coordination Polymers as Template for Mesoporous Silica Films: A Novel Composite Material Fe(Htrz) 3 @SiO 2 with Remarkable Electrochemical Properties
Résumé
While attempting to confine Fe(Htrz)3 (Htrz = 1,2,4,-1H-triazole) into a mesoporous silica matrix during its formation by electrochemically assisted self-assembly (EASA), we have discovered that such spin crossover complex is likely to act as the template (in place of the surfactant species) to form in one step a composite mesoporous material (Fe(Htrz)3@SiO2). The EASA method usually leads to the vertical
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