Coordination Polymers as Template for Mesoporous Silica Films: A Novel Composite Material Fe(Htrz) 3 @SiO 2 with Remarkable Electrochemical Properties - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Chemistry of Materials Année : 2019

Coordination Polymers as Template for Mesoporous Silica Films: A Novel Composite Material Fe(Htrz) 3 @SiO 2 with Remarkable Electrochemical Properties

Résumé

While attempting to confine Fe(Htrz)3 (Htrz = 1,2,4,-1H-triazole) into a mesoporous silica matrix during its formation by electrochemically assisted self-assembly (EASA), we have discovered that such spin crossover complex is likely to act as the template (in place of the surfactant species) to form in one step a composite mesoporous material (Fe(Htrz)3@SiO2). The EASA method usually leads to the vertical
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hal-02324674 , version 1 (26-11-2020)

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Samuel Ahoulou, Neus Vilà, Sébastien Pillet, Dominik Schaniel, Alain Walcarius. Coordination Polymers as Template for Mesoporous Silica Films: A Novel Composite Material Fe(Htrz) 3 @SiO 2 with Remarkable Electrochemical Properties. Chemistry of Materials, 2019, 31 (15), pp.5796-5807. ⟨10.1021/acs.chemmater.9b01879⟩. ⟨hal-02324674⟩
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