Further studies on the photoreactivities of ruthenium–nitrosyl complexes with terpyridyl ligands - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue New Journal of Chemistry Année : 2019

Further studies on the photoreactivities of ruthenium–nitrosyl complexes with terpyridyl ligands

Résumé

This study focuses on the two cis/trans-(Cl,Cl)-[Ru(R-Phtpy)Cl2(NO)]+ isomers, where the R group is a NEt2 substituent on the 4′-position of the phenylterpyridine (Phtpy) moiety. The photophysical characteristic properties of the two isomers and those of one nitrosamine derivative are described. The NO release properties are evaluated and show that the cis isomer is the most efficient with a good quantum yield of NO release. The X-ray structures of three ruthenium–nitrosyl complexes and of a photoproduct are presented.
Fichier principal
Vignette du fichier
New. J. Chem.SASAKI.pdf (953.9 Ko) Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)
Loading...

Dates et versions

hal-02321845 , version 1 (04-11-2020)

Identifiants

Citer

Isabelle Sasaki, Silvia Amabilino, Sonia Mallet-Ladeira, Marine Tassé, Alix Sournia-Saquet, et al.. Further studies on the photoreactivities of ruthenium–nitrosyl complexes with terpyridyl ligands. New Journal of Chemistry, 2019, 43 (28), pp.11241-11250. ⟨10.1039/C9NJ02398D⟩. ⟨hal-02321845⟩
41 Consultations
104 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More